Synthesis of water-soluble bis-N,O-chelate nickel(II) complexes based on new ligands – P-pyridyl-containing phospholane oxides
Sign Up to like & getrecommendations! Published in 2018 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-018-2203-7
Abstract: A series of new N,O-hybrid ligands was synthesized by oxidation of pyridyl-substituted phospholanes. These ligands were employed in the first synthesis of water-soluble mononuclear nickel(II) complexes [NiL2(H2O)2](BF4)2 and [NiL2(MeCN)2](BF4)2. Physicochemical properties and crystalline structures of… read more here.
Keywords: nickel complexes; soluble bis; synthesis water; water soluble ... See more keywords
Synthesis of water-free PEDOT with polyvinylpyrrolidone stabilizer in organic dispersant system
Sign Up to like & getrecommendations! Published in 2018 at "Organic Electronics"
DOI: 10.1016/j.orgel.2017.11.035
Abstract: Abstract Poly (3, 4-ethylenedioxythiophene): tosylate (PEDOT: Tos) is synthesized by chemical oxidative polymerization with polyvinylpyrrolidone (PVP) as stabilizer in organic solvent. The effects of different molecular weight and additive amount of PVP stabilizer, various volume… read more here.
Keywords: pedot; system; synthesis water; stabilizer ... See more keywords
Synthesis of Water-Soluble Far-Red-Emitting Amphiphilic BODIPY Dyes
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DOI: 10.1021/acsomega.8b01487
Abstract: We report the synthesis of two water-soluble BODIPY dyes with far-red absorption and near-infrared fluorescence following cell membrane insertion. Introduction of dicationic or dianionic groups imparts water solubility and prevents translocation of the dye through… read more here.
Keywords: water; synthesis water; water soluble; bodipy dyes ... See more keywords
Tandem deprotection/coupling for peptide synthesis in water at room temperature
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DOI: 10.1039/c7gc01575e
Abstract: A tandem deprotection/coupling sequence is reported for solution-phase peptide synthesis in water under micellar catalysis conditions using the designer surfactant TPGS-750-M. Cbz deprotection followed by peptide coupling in the presence of COMU and 2,6-lutidine afforded… read more here.
Keywords: tandem deprotection; synthesis water; deprotection; peptide synthesis ... See more keywords
Solid-State Synthesis of Water-Soluble Chitosan-g-Hydroxyethyl Cellulose Copolymers
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DOI: 10.3390/polym12030611
Abstract: Graft copolymers of chitosan with cellulose ether have been obtained by the solid-state reactive mixing of chitin, sodium hydroxide and hydroxyethyl cellulose under shear deformation in a pilot twin-screw extruder. The structure and composition of… read more here.
Keywords: solid state; state synthesis; synthesis water; hydroxyethyl cellulose ... See more keywords