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Published in 2020 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2020.108443
Abstract: Abstract Starting from substituted 1,3-diynes a straightforward strategy to prepare phospholes has been explored for a series of substituents with electron poor and electron rich character (C6H5, C6H4CF3, C6F4OCH3, C5H4N, C4H3S, C4H3O, C6H4OCH3). The reaction…
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Keywords:
luminescence tuning;
substituted phospholes;
series;
luminescence ... See more keywords
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Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b13818
Abstract: An aza analogue of the Rubottom oxidation is reported. This facile transformation takes place at ambient temperature and directly converts silyl enol ethers to the corresponding primary α-aminoketones. The use of hexafluoroisopropanol (HFIP) as the…
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Keywords:
aza rubottom;
rubottom oxidation;
oxidation synthetic;
primary aminoketones ... See more keywords
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Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05241g
Abstract: A perfluoroisopropenyl ether terminated oligo(hexafluoropropylene oxide), a perfluoropolyalkyl ether macromonomer for radical copolymerization, has been prepared. The synthesis was achieved through a carefully controlled defluorination of a highly unstable lithium perfluorocarbanion intermediate. Several undesired pathways…
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Keywords:
synthetic access;
radical copolymerization;
perfluoroisopropenyl ether;
access elusive ... See more keywords
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Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc01447h
Abstract: Calix[3]pyrroles were synthesized for the first time. These macrocycles display versatile guest binding ability based on the bridges connecting the two α-positions of the tripyrrane moiety e.g. with an ethene bridge they showed colorimetric sensing…
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Keywords:
calix pyrroles;
synthetic access;
chemistry;
pyrroles via ... See more keywords
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3
Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt01357j
Abstract: Green and sustainable access to chiral and achiral gold-IBiox complexes is reported. The gold complexes were synthesized using a simple, air-tolerant, weak base protocol carried out in a green solvent. Their catalytic activity was examined…
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Keywords:
access ibiox;
ibiox complexes;
synthetic access;
simple synthetic ... See more keywords
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Published in 2022 at "Molecules"
DOI: 10.3390/molecules27113583
Abstract: α-Haloketones play an essential role in the synthesis of complex N-, S-, O-heterocycles; of which some exhibit a remarkable biological activity. Research further illustrated that α-bromo-, α-chloro-, and α-iodoketones are key precursors for blockbuster pharmacological…
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Keywords:
aromatic haloketones;
access aromatic;
synthetic access;
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Published in 2022 at "Pharmaceuticals"
DOI: 10.3390/ph16010040
Abstract: Psychedelics are used for various pathologies of the central nervous system and are currently the subject of much research, some of which relates to the compounds contained in various Psilocybe-type hallucinogenic mushrooms. It is difficult,…
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Keywords:
access therapeutic;
synthetic access;
review synthetic;
therapeutic compounds ... See more keywords