Synthetic access and luminescence tuning in a series of β-H and β-silyl substituted phospholes
Sign Up to like & getrecommendations! Published in 2020 at "Dyes and Pigments"
DOI: 10.1016/j.dyepig.2020.108443
Abstract: Abstract Starting from substituted 1,3-diynes a straightforward strategy to prepare phospholes has been explored for a series of substituents with electron poor and electron rich character (C6H5, C6H4CF3, C6F4OCH3, C5H4N, C4H3S, C4H3O, C6H4OCH3). The reaction… read more here.
Keywords: luminescence tuning; substituted phospholes; series; luminescence ... See more keywords
Aza-Rubottom Oxidation: Synthetic Access to Primary α-Aminoketones.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b13818
Abstract: An aza analogue of the Rubottom oxidation is reported. This facile transformation takes place at ambient temperature and directly converts silyl enol ethers to the corresponding primary α-aminoketones. The use of hexafluoroisopropanol (HFIP) as the… read more here.
Keywords: aza rubottom; rubottom oxidation; oxidation synthetic; primary aminoketones ... See more keywords
Synthetic access to an elusive high-temperature perfluoroisopropenyl ether prepolymer for radical copolymerization.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc05241g
Abstract: A perfluoroisopropenyl ether terminated oligo(hexafluoropropylene oxide), a perfluoropolyalkyl ether macromonomer for radical copolymerization, has been prepared. The synthesis was achieved through a carefully controlled defluorination of a highly unstable lithium perfluorocarbanion intermediate. Several undesired pathways… read more here.
Keywords: synthetic access; radical copolymerization; perfluoroisopropenyl ether; access elusive ... See more keywords
Synthetic access to calix[3]pyrroles via meso-expansion: hosts with diverse guest chemistry.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc01447h
Abstract: Calix[3]pyrroles were synthesized for the first time. These macrocycles display versatile guest binding ability based on the bridges connecting the two α-positions of the tripyrrane moiety e.g. with an ethene bridge they showed colorimetric sensing… read more here.
Keywords: calix pyrroles; synthetic access; chemistry; pyrroles via ... See more keywords
Simple synthetic access to [Au(IBiox)Cl] complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt01357j
Abstract: Green and sustainable access to chiral and achiral gold-IBiox complexes is reported. The gold complexes were synthesized using a simple, air-tolerant, weak base protocol carried out in a green solvent. Their catalytic activity was examined… read more here.
Keywords: access ibiox; ibiox complexes; synthetic access; simple synthetic ... See more keywords
Synthetic Access to Aromatic α-Haloketones
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27113583
Abstract: α-Haloketones play an essential role in the synthesis of complex N-, S-, O-heterocycles; of which some exhibit a remarkable biological activity. Research further illustrated that α-bromo-, α-chloro-, and α-iodoketones are key precursors for blockbuster pharmacological… read more here.
Keywords: aromatic haloketones; access aromatic; synthetic access;
A Review of Synthetic Access to Therapeutic Compounds Extracted from Psilocybe
Sign Up to like & getrecommendations! Published in 2022 at "Pharmaceuticals"
DOI: 10.3390/ph16010040
Abstract: Psychedelics are used for various pathologies of the central nervous system and are currently the subject of much research, some of which relates to the compounds contained in various Psilocybe-type hallucinogenic mushrooms. It is difficult,… read more here.
Keywords: access therapeutic; synthetic access; review synthetic; therapeutic compounds ... See more keywords