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   Articles with "synthetic applications" as a keyword



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Synthetic Applications of Sulfonium Salts

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recommendations! Published in 2020 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.202000249

Abstract: This minireview aims to cover the developments over the past two decades in the chemistry of sulfonium salts. Specifically, insight is provided into the synthetic strategies available for the preparation of these compounds, the different… read more here.

Keywords: sulfonium salts; sulfonium; chemistry; applications sulfonium ... See more keywords
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Palladium-Catalyzed Asymmetric Allylic C-H Functionalization: Mechanism, Stereo- and Regioselectivities, and Synthetic Applications.

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recommendations! Published in 2020 at "Accounts of chemical research"

DOI: 10.1021/acs.accounts.0c00477

Abstract: ConspectusAsymmetric functionalization of inert C-H bonds is undoubtedly a synthetically significant yet challenging bond-forming process, allowing for the preparation of densely functionalized molecules from abundantly available feedstocks. In the past decade, our group and others… read more here.

Keywords: functionalization; catalyzed asymmetric; allylic alkylation; asymmetric allylic ... See more keywords

Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications.

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recommendations! Published in 2017 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.7b00445

Abstract: A cobalt-catalyzed method for the 1,1-diboration of terminal alkynes with bis(pinacolato)diboron (B2Pin2) is described. The reaction proceeds efficiently at 23 °C with excellent 1,1-selectivity and broad functional group tolerance. With the unsymmetrical diboron reagent PinB-BDan… read more here.

Keywords: diboration terminal; terminal alkynes; cobalt catalyzed; diboration ... See more keywords

Synthetic applications of NHPs: from the hydride pathway to a radical mechanism.

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recommendations! Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc04844b

Abstract: The unique heterocyclic skeletons of N-heterocyclic phosphines (NHPs) endow them with excellent hydridic reactivity, which has enabled NHPs to be applied in a great array of catalytic hydrogenations of unsaturated substrates in the past few… read more here.

Keywords: nhps hydride; synthetic applications; applications nhps; hydride pathway ... See more keywords