LAUSR

Synthetic [NiFe] models with a fluxional CO ligand.

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1 Published in 2017 at "Dalton transactions"

DOI: 10.1039/c7dt02892j

Abstract: A [NiFe] complex [(dppe)Ni(pdt)FeCp*(CO)]+ was isolated and characterized as two isomers [1(CO)]+ and [1'(CO)]+. Heating the solution of [1(CO)]+ allowed it to convert into [1'(CO)]+. The one-electron oxidation of [1'(CO)]+ to [1'(CO)]2+ induced fluxional CO… read more here.

Keywords: nife; synthetic nife; nife models; fluxional ligand ... See more keywords