Alkynyl Acylazolium: a Versatile 1,3-Bielectrophilic 3C-Synthon in NHC-Organocatalysis.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical record"
DOI: 10.1002/tcr.202300046
Abstract: N-Heterocyclic carbene (NHC) organocatalysis has emerged as a powerful tool in the field of modern organic synthesis especially in the asymmetric construction of various cyclic skeletons. As an emerging NHC-bound 1,3-bielectrophilic intermediate, alkynyl acylazolium has… read more here.
Keywords: nhc organocatalysis; synthon; alkynyl acylazolium;
Parent Cyclopentadienyl Ruthenium(II) Chloride Synthon: Derivatization to CpRu Amido, Imido, and Oxo Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00576
Abstract: The complex salt [CpRu(η6-C10H8)][(CpRu)2(μ-Cl)3] ([1][2]) was synthesized and found to be a useful CpRuCl synthon. The ions [1]+ and [2]− cleanly comproportionate into monomeric CpRuCl(L)2 complex... read more here.
Keywords: ruthenium chloride; synthon; chloride synthon; parent cyclopentadienyl ... See more keywords
Acid···Amide Supramolecular Synthon in Cocrystals: From Spectroscopic Detection to Property Engineering.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b02435
Abstract: The acid···amide dimer heterosynthon in cocrystals of aromatic acids and primary amides is identified by marker peaks in the IR spectra that are characteristic of individual N-H···O and O-H···O interactions and also of the extended… read more here.
Keywords: engineering; acid amide; amide supramolecular; synthon ... See more keywords