Structural evolution from preorganized mononuclear triazamacrocyclic metalloligands to polynuclear metallocages and heterometallic 2D layers: modular architectures, assembly tracking and magnetic properties.
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DOI: 10.1039/d2dt02186b
Abstract: The reaction of a macrocyclic ligand 1,4,7-triazacyclononane-1,4,7-tripropionic acid (tacntpH3) with Ni(II)/Co(II) sources in the presence or absence of lanthanide cations yielded a series of doubly mononuclear ionic complexes (H3O+)[LnIII(H2O)8][NiII(tacntp)]4 (1-NiLn, Ln = La, Ce, Yb)… read more here.
Keywords: modular architectures; tacntp; h2o; preorganized mononuclear ... See more keywords