Taming the Chlorine Radical: Enforcing Steric Control over Chlorine-Radical-Mediated C-H Activation.
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DOI: 10.1021/jacs.1c13333
Abstract: Chlorine radicals readily activate C-H bonds, but the high reactivity of these intermediates precludes their use in regioselective C-H functionalization reactions. We demonstrate that the secondary coordination sphere of a metal complex can confine photoeliminated… read more here.
Keywords: chlorine radical; enforcing steric; taming chlorine; radical enforcing ... See more keywords