Taming a silyldiium cation and its reactivity towards sodium phosphaethynolate.
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DOI: 10.1039/c8cc07632d
Abstract: A dicationic bis(NHC)-stabilised silyldiium complex, [bis(NHC)-SiPh2]2+ (72+) (bis(NHC) = [CH2(NC3H2NDipp)2], Dipp = 2,6-iPr2C6H3), was synthesised for the first time. It reacts with sodium phosphaethynolate (NaOCP) as a source of monoanionic phosphorus to give the P-insertion… read more here.
Keywords: bis nhc; sodium phosphaethynolate; bis; silyldiium cation ... See more keywords