Selective Oxygenation of Cyclohexene by Dioxygen via an Iron(V)-Oxo Complex-Autocatalyzed Reaction.
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DOI: 10.1021/acs.inorgchem.7b00220
Abstract: An iron complex with a tetraamido macrocyclic ligand, [(TAML)FeIII]-, was found to be an efficient and selective catalyst for allylic oxidation of cyclohexene by dioxygen (O2); cyclohex-2-enone was obtained as the major product along with… read more here.
Keywords: cyclohexene dioxygen; iron; taml feiii; cyclohexene ... See more keywords