Hydride–Rhodium(III)-N-Heterocyclic Carbene Catalyst for Tandem Alkylation/Alkenylation via C–H Activation
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DOI: 10.1021/acscatal.9b01233
Abstract: The unsaturated hydride complex RhClH{κ2-N,C-(C11H8N)}(IPr) {IPr = 1,3-bis-(2,6-diisopropylphenyl)imidazolin-2-carbene} (2) has been prepared via C–H activation of 2-phenylpyridine and fully characterized by spectroscopic methods and X-ray diffraction analysis. Complex 2 efficiently catalyzes the isomerization of terminal… read more here.
Keywords: hydride; alkylation alkenylation; tandem alkylation; alkylation ... See more keywords