Bifunctional Janus silica spheres for Pickering interfacial tandem catalysis.
Sign Up to like & getrecommendations! Published in 2021 at "ChemSusChem"
DOI: 10.1002/cssc.202101238
Abstract: Nature provides much inspiration for the design of multistep conversion processes, with numerous reactions running simultaneously and without interference in cells, for example. A key challenge in mimicking nature's strategies is to compartmentalize incompatible reagents… read more here.
Keywords: bifunctional janus; base; catalysis; tandem catalysis ... See more keywords
Transformation of carbohydrates to 5-hydroxymethylfurfural with high efficiency by tandem catalysis
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Cleaner Production"
DOI: 10.1016/j.jclepro.2020.123023
Abstract: Abstract Production of 5-hydroxymethylfurfural (HMF) is a pivotal step in biorefinery. However, the intrinsic HMF production efficiency in traditional catalytic systems are low owing to the side-reactions. Here we report the highly efficient transformation of… read more here.
Keywords: transformation carbohydrates; efficiency; carbohydrates hydroxymethylfurfural; tandem catalysis ... See more keywords
Heterogeneous Diels-Alder tandem catalysis for converting cellulose and polyethylene into BTX.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of hazardous materials"
DOI: 10.1016/j.jhazmat.2021.125418
Abstract: Producing biomass-derived aromatic hydrocarbons via controllable Diels-Alder reactions is a promising approach to recover energy and chemicals from waste streams. A tandem Diels-Alder catalysis consisting of SAPO-34 and Fe/HZSM-5 (stacked catalysis or mixed catalysis) was… read more here.
Keywords: diels alder; btx; catalysis; tandem catalysis ... See more keywords
Reducing Challenges in Organic Synthesis with Stereoselective Hydrogenation and Tandem Catalysis.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c00750
Abstract: Tandem catalysis enables the rapid construction of complex architectures from simple building blocks. This Perspective shares our interest in combining stereoselective hydrogenation with transformations such as isomerization, oxidation, and epimerization to solve diverse challenges. We… read more here.
Keywords: stereoselective hydrogenation; reducing challenges; hydrogenation; tandem catalysis ... See more keywords
Tandem Catalysis: Transforming Alcohols to Alkenes by Oxidative Dehydroxymethylation.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b06069
Abstract: We report a Rh-catalyst for accessing olefins from primary alcohols by a C-C bond cleavage that results in dehomologation. This functional group interconversion proceeds by an oxidation-dehydroformylation enabled by N, N-dimethylacrylamide as a sacrificial acceptor… read more here.
Keywords: oxidative dehydroxymethylation; dehydroxymethylation; alcohols alkenes; tandem catalysis ... See more keywords
Tandem catalysis in multicomponent solvent-free biofluids.
Sign Up to like & getrecommendations! Published in 2019 at "Nanoscale"
DOI: 10.1039/c9nr06045f
Abstract: Enzymes are widely employed to reduce the environmental impact of chemical industries as biocatalysts improve productivity and offer high selectively under mild reaction conditions in a diverse range of chemical transformations. The poor stability of… read more here.
Keywords: multicomponent solvent; free biofluids; tandem catalysis; catalysis multicomponent ... See more keywords
A naphthalene-based heterobimetallic triazolylidene IrIII/PdII complex: regioselective to regiospecific C-H activation, tandem catalysis and a copper-free Sonogashira reaction.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03508a
Abstract: Heterobimetallic complexes featuring mesoionic carbene (MIC) donor ligands are gaining enormous popularity in tandem catalysis owing to the combined action of two different metal centers during catalysis. A rare version of the heterobimetallic PdII/IrIII complex… read more here.
Keywords: regioselective regiospecific; naphthalene based; tandem catalysis; pdii ... See more keywords