Tandem deoxygenative hydrosilation of carbon dioxide with a cationic scandium hydridoborate and B(C6F5)3.
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DOI: 10.1039/c9dt04323c
Abstract: A scandium hydridoborate complex supported by the dianionic pentadentate ligand B2Pz4Py is prepared via hydride abstraction from the previously reported scandium hydride complex with tris-pentafluorophenyl borane. Exposure of [(B2Pz4Py)Sc][HB(C6F5)3] to CO2 immediately forms [(B2Pz4Py)Sc][HCOOB(C6F5)3] at… read more here.
Keywords: scandium hydridoborate; tandem deoxygenative; c6f5; hydrosilation ... See more keywords