β-Silyl-Assisted Tandem Diels-Alder/Nazarov Reaction of 1-Aryl-3-(trimethylsilyl) Ynones.
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DOI: 10.1021/acs.orglett.7b00911
Abstract: A one-pot tandem Diels-Alder/Nazarov reaction of 1-aryl-3-(trimethylsilyl) ynones has been achieved to generate carbo- and heterocyclic fused ring systems in good to excellent yields. The β-silyl effect is instrumental in accessing this otherwise challenging cascade… read more here.
Keywords: diels alder; nazarov reaction; tandem diels; reaction ... See more keywords
Tandem Diels-Alder reaction overrules entropy: the gate to a thermally stable, yet thermally recyclable furan-based polymers
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DOI: 10.1039/d4gc04846f
Abstract: The study investigates the kinetics and thermodynamics of the reversible tandem Diels-Alder (tDA) reaction between difuranic compounds and maleimides, leading to the quantitative formation of tDA adducts at rates comparable... read more here.
Keywords: reaction overrules; overrules entropy; alder reaction; diels alder ... See more keywords