Ultrafine Ruthenium Clusters Shell-Embedded Hollow Carbon Spheres as Nanoreactors for Channel Microenvironment-Modulated Furfural Tandem Hydrogenation.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202201361
Abstract: Rationally modulating the catalytic microenvironment is important for targeted induction of specific molecular behaviors to fulfill complicated catalytic purposes. Herein, a metal pre-chelating assisted assembly strategy is developed to facilely synthesize the hollow carbon spheres… read more here.
Keywords: tandem hydrogenation; ruthenium clusters; ultrafine ruthenium; microenvironment ... See more keywords
Synthesis of Biobased Long-Chain Polyesters by Acyclic Diene Metathesis Polymerization and Tandem Hydrogenation and Depolymerization with Ethylene
Sign Up to like & getrecommendations! Published in 2020 at "ACS Omega"
DOI: 10.1021/acsomega.0c01965
Abstract: Acyclic diene metathesis (ADMET) polymerization of biobased α,ω-dienes of bis(undec-10-enoate) with diols (1,4-butanediol, isosorbide, isomannide, and 1,4-cyclohexanedimethanol) afforded high-molecular weight unsaturated polyesters, and subsequent tandem hydrogenation (H2 1.0 MPa, 50 °C, 3 h) gave the… read more here.
Keywords: tandem hydrogenation; polymerization; diene metathesis; acyclic diene ... See more keywords