Hydroformylation and tandem isomerization–hydroformylation of n-decenes using a rhodium-BiPhePhos catalyst: Kinetic modeling, reaction network analysis and optimal reaction control
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2016.12.070
Abstract: Abstract The rhodium-BiPhePhos catalyzed hydroformylation of n-decenes, as representative long-chain olefins, was investigated in this study experimentally and theoretically. Besides hydroformylation activity, the used catalyst enables significant double bond isomerization which is an essential side… read more here.
Keywords: isomerization hydroformylation; hydroformylation; tandem isomerization; reaction ... See more keywords
Ligand-Controlled Nickel-Catalyzed Tandem Isomerization/Regiodivergent Hydroheteroarylation of α-Alkenes with Heteroarenes.
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DOI: 10.1021/acs.orglett.2c03689
Abstract: We herein describe an accessible ligand-controlled nickel-catalyzed tandem isomerization/regiodivergent hydroheteroarylation of α-alkenes with a series of heteroarenes, wherein the NHC ligand of heteroleptic Ni(II) complexes of the type Ni(NHC)[P(OEt)3]Br2 displayed significant effects on regulation. In… read more here.
Keywords: catalyzed tandem; controlled nickel; nickel catalyzed; isomerization ... See more keywords