Hypoiodite-Catalyzed Chemoselective Tandem Oxidation of Homotryptamines to Peroxy- and Epoxytetrahydropyridoindolenines.
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DOI: 10.1021/acs.orglett.0c03001
Abstract: We developed the hypoiodite-catalyzed tandem dearomative peroxycyclization of homotryptamine derivatives to peroxytetrahydropyridoindolenines under mild conditions. During the course of a mechanistic study, we found that a tandem oxidative cyclization/epoxidation as an unexpected reaction proceeded in… read more here.
Keywords: oxidation; tandem oxidation; oxidation homotryptamines; chemoselective tandem ... See more keywords