PdAu@MIL-100(Fe) cooperatively catalyze tandem reactions between amines and alcohols for efficient N-alkyl amines syntheses under visible light
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.02.033
Abstract: Abstract PdAu@MIL-100(Fe), with PdAu alloy nanoparticles of ca. 1.7 nm encapsulated inside MIL-100(Fe) cavities, were prepared via a double-solvent impregnation followed by photoreduction. As compared with bare Pd@MIL-100(Fe), bimetallic PdAu@MIL-100(Fe) showed superior activities for the tandem… read more here.
Keywords: tandem reactions; reactions amines; pdau mil; reaction ... See more keywords
Manipulating Solvothermal Coordination-Catalyzed In Situ Tandem Reactions to Construct Dysprosium-Based Complexes with Different Shapes and Zero-Field SMM Behaviors.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03238
Abstract: By changing the coordination anions (OAc- and Cl-), reaction temperature, solvent, and ligand substituents, four Dy(III)-based complexes were obtained by directed synthesis, which are [Dy4(L1)2(L2)2(OAc)4]·4C2H5OH·3H2O (1, L1 = 1,3,4-thiadiazole-2,5-diamine, H4L2 = 6,6'-(((1,3,4-thiadiazole-2,5-diyl)bis(azanediyl))bis(((3-ethoxy-2-hydroxybenzyl)oxy)methylene))bis(2-ethoxyphen), [Dy4(L3)4(OAc)4]·C2H5OH·H2O (2, H3L3… read more here.
Keywords: tandem reactions; based complexes; situ tandem; zero field ... See more keywords
Catalytic Asymmetric Umpolung Tandem Reactions of Hemiacetals via Dinuclear Zinc Cooperative Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c00913
Abstract: The umpolung activity of hemiacetals serving as α-carbon nucleophiles has been reported via dinuclear zinc cooperative catalysis. This umpolung strategy has been applied to catalytic asymmetric tandem reactions of 1-tosylindoline-2,3-diols with β,γ-unsaturated-α-keto compounds, providing a… read more here.
Keywords: dinuclear zinc; tandem reactions; cooperative catalysis; via dinuclear ... See more keywords
Tandem Reactions for the Synthesis of High-Density Polycyclic Biofuels with a Double/Triple Hexane Ring
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c07241
Abstract: Synthesizing high-density fuels from non-food biomass is of great interest in the field of biomass conversion because they can increase the loading capability and travel distance of vehicles and aircraft as compared to conventional low-density… read more here.
Keywords: density; tandem reactions; high density; synthesis high ... See more keywords