Organomagnesia: Reversibly High Carbon Dioxide Uptake by Magnesium Pyrazolates
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202403295
Abstract: A series of new pyrazolate and mixed pyrazolate/pyrazole magnesium complexes is described and their reactivity toward carbon dioxide is examined. The dimeric complex [Mg(pztBu,tBu)2]2 inserts CO2 instantly and quantitatively forming the tetrameric complex [Mg(CO2·pztBu,tBu)2]4 and… read more here.
Keywords: carbon dioxide; tbu; magnesium pyrazolates;
Evaluation of the tert-butyl group as a probe for NMR studies of macromolecular complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of biomolecular NMR"
DOI: 10.1007/s10858-021-00380-y
Abstract: The development of methyl transverse relaxation optimized spectroscopy has greatly facilitated the study of macromolecular assemblies by solution NMR spectroscopy. However, limited sample solubility and stability has hindered application of this technique to ongoing studies… read more here.
Keywords: tbu; group; tbu groups; tbu resonances ... See more keywords
Coordination-promoted photoluminescence induced by configuration twisting regulation
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2020.117783
Abstract: ABSTRACT In this work, we reported a coordination-promoted photoluminescence (CPPL) phenomenon of a new organometallic complex tBu(ONO)-W formed by ligand tBu(ONO) and metal tungsten for the first time. At the same time, the photoluminescence mechanisms… read more here.
Keywords: tbu; tbu ono; coordination; photoluminescence ... See more keywords
2-Phosphine-pyridine-N-oxide palladium and nickel catalysts for ethylene polymerization and copolymerization with polar monomers
Sign Up to like & getrecommendations! Published in 2020 at "Polymer"
DOI: 10.1016/j.polymer.2020.122410
Abstract: Abstract A new family of [P,O] late transition metal catalysts, namely 2-phosphine-pyridine-N-oxide palladium complexes Pd1~Pd4 {[κ2(P,O)-2-Ar2P-6-R-(C5H3NO)]PdMeCl} (Pd1: Ar = Ph, R = H; Pd2: Ar = 2-MeO-C6H4, R = H; Pd3: Ar = Ph, R = tBu; Pd4: Ar = 2-MeO-C6H4, R = tBu) and nickel complexes… read more here.
Keywords: tbu; nickel; oxide palladium; pyridine oxide ... See more keywords
An Azide Adduct of Ti(II) with a Sterically Encumbering Trityl Azide and Independent Synthesis of a Bulky Ti(IV) Imido and Its Isomer.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c04975
Abstract: We report here the synthesis and characterization of a bulky titanium(IV) imido via the bimolecular deazotation of trityl azide by the Ti(II) precursor [(Tp3-tBu,5-Me)TiCl] (1, Tp3-tBu,5-Me = hydrido(tris(3-methyl-5-tert-butylpyrazolyl)borate)). The sterically encumbering trityl substituent on an… read more here.
Keywords: tbu; trityl azide; tp3 tbu; encumbering trityl ... See more keywords
Terminal {Ni(II)-SH} complex promoted anaerobic catalytic sulfur atom transfer reaction: implication to the sulfide oxidase function of Cu/Zn-superoxide dismutase.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt01364f
Abstract: In mitochondria, the detoxification of molar excess H2S as polysulfide proceeded via an oxidation process promoted by Cu/Zn containing superoxide dismutase (SOD1) enzyme, which has been very recently reported as the alternative enzyme for cytosolic… read more here.
Keywords: tbu; reaction; sulfide oxidase; catalytic sulfur ... See more keywords
Adaptive photoluminescence through a bioinspired antioxidative mechanism
Sign Up to like & getrecommendations! Published in 2024 at "Chemical Science"
DOI: 10.1039/d4sc06096b
Abstract: Transition metal complexes are archetypal luminescent probes that are widely used for various applications ranging from optoelectronics to biomedicine. However, they face significant challenges such as photobleaching and photooxidative stress, which limit their performance. Herein,… read more here.
Keywords: tbu; adaptive photoluminescence; bioinspired antioxidative; photoluminescence bioinspired ... See more keywords
Unusual coordination of mononuclear cobalt(III) complexes with sterically demanding Schiff bases: synthesis, spectroscopy, electrochemistry, crystallography, DNA binding, and theoretical investigation
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2017.1380196
Abstract: Abstract Three mononuclear CoIII complexes, [Co(L1 tBu)(bdbp)]·2EtOH (1), [Co(L2 tBu)(bdbp)] (2), and [Co(L3 tBu)2]ClO4 (3) (where H2L1 tBu = bis[{6-benzoyl-4-tert-butyl-2-hydroxyphenyl}benzi-midoyl]-1,2-ethane, H2L2 tBu = bis[{6-benzoyl-4-tert-butyl-2-hydroxyphenyl}benzimidoyl]-1,3-propane, bdbpH = 4-tert-butyl-2,6-dibenzoylphenol and HL3 tBu = 2-{N-(4-amino-butyl)benzimidoyl}-6-benzoyl-4-tert-butylphenol), have been synthesized… read more here.
Keywords: tbu; schiff bases; spectroscopy; dna binding ... See more keywords
Diagnosis and Treatment of Tubercular Uveitis in Taiwan - Consensus of Expert Panels.
Sign Up to like & getrecommendations! Published in 2023 at "Ocular immunology and inflammation"
DOI: 10.1080/09273948.2023.2208660
Abstract: There is currently a lack of guidelines with regard to tubercular uveitis (TBU) management in Taiwan. We therefore propose an evidence-based consensus on the management for TBU. The Taiwan Ocular Inflammation Society conducted a meeting… read more here.
Keywords: tubercular uveitis; consensus; diagnosis; tbu ... See more keywords
Synthesis and Photophysical Evaluation of Isoleptic Pt(II) and Pd(II) Complexes Utilizing N^N^N Ligands as Luminophoric Chelators with Different Ancillary Ligands
Sign Up to like & getrecommendations! Published in 2024 at "Inorganics"
DOI: 10.3390/inorganics12020058
Abstract: We herein report on the synthesis and structural characterization, as well as on the photophysical properties, of a series of isoleptic Pt(II) and Pd(II) complexes featuring tridentate N^N^N chelators as luminophores while bearing diverse ancillary… read more here.
Keywords: tbu; isoleptic complexes; photophysical evaluation; ancillary ligands ... See more keywords