An N‐heterocyclic Carbene TCNE Zwitterion: Experimental and Theoretical Study on its Formation and Reactivity
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201601648
Abstract: A direct addition of tetracyanoethylene (TCNE) at the carbene center of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) has been successfully demonstrated. The IPr-TCNE adduct, zwitterion 1, clearly differs from the typical products of [2+1] cyclization obtained from the reaction… read more here.
Keywords: study; tcne; reactivity; carbene ... See more keywords
Lin@Tetracyanoethylene (n = 1–4) systems: Lithium salt vs lithium electride
Sign Up to like & getrecommendations! Published in 2019 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2018.12.014
Abstract: Abstract Electrides are interesting and promising materials with cavity-trapped electrons which can be used as source of electron donor in different systems. Hereby, we have explored the possible formation of electride materials based on tetracyanoethylene… read more here.
Keywords: tcne backbone; systems lithium; tcne; lithium electride ... See more keywords
Permanent Porosity in the Room-Temperature Magnet and Magnonic Material V(TCNE)2
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DOI: 10.1021/acscentsci.3c00053
Abstract: Materials that simultaneously exhibit permanent porosity and high-temperature magnetic order could lead to advances in fundamental physics and numerous emerging technologies. Herein, we show that the archetypal molecule-based magnet and magnonic material V(TCNE)2 (TCNE =… read more here.
Keywords: magnet; room temperature; temperature; permanent porosity ... See more keywords