Photoinduced Jahn-Teller switch in Mn(III) terpyridine complexes.
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DOI: 10.1039/d2dt00889k
Abstract: Ultrafast transient absorption spectra were recorded for [Mn(terpy)X3], where X = Cl, F, and N3, to explore photoinduced switching from axial to equatorial Jahn-Teller (JT) distortion. Strong oscillations were observed in the transients, corresponding to… read more here.
Keywords: teller; photoinduced jahn; terpyridine; jahn teller ... See more keywords
Equatorial restriction of the photoinduced Jahn-Teller switch in Mn(III)-cyclam complexes
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc01506h
Abstract: Ultrafast transient absorption spectra were recorded for solutions of [MnIII(cyclam)(H2O)(OTf)][OTf]2 (cyclam = 1,4,8,11-tetraazacyclotetradecane and OTf = Trifluoromethanesulfonate) in water to explore the possibility to restrict the equatorial expansion following photoexcitation... read more here.
Keywords: cyclam; photoinduced jahn; equatorial restriction; restriction photoinduced ... See more keywords