Telomerization of 1,3‐Butadiene with Carbon Dioxide: A Highly Efficient Process for δ‐Lactone Generation
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DOI: 10.1002/cctc.201701058
Abstract: A very efficient and selective telomerization of 1,3‐butadiene with CO2 that leads to the δ‐lactone (3‐ethylidene‐6‐vinyltetrahydro‐2H‐pyran‐2‐one) was obtained using palladium acetate and tris(p‐methoxyphenyl)phosphine as a catalyst in the presence of p‐hydroquinone, N,N‐diisopropylethylamine, and acetonitrile. A… read more here.
Keywords: telomerization butadiene; lactone; butadiene carbon; telomerization ... See more keywords
Towards a process for the telomerization of butadiene with N-methylglucamine
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DOI: 10.1016/j.ces.2018.02.012
Abstract: Abstract The telomerization of 1,3-dienes with functionalized nucleophiles presents an atom efficient and selective synthesis of potential non-ionic surfactants. Crucial for application of these synthetic pathways is the effective recycling of the homogeneous palladium catalyst.… read more here.
Keywords: telomerization butadiene; methylglucamine; butadiene; telomerization ... See more keywords
Synthesis and self-assembly of amphiphilic heterografted molecular brushes prepared by telomerization
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DOI: 10.1016/j.eurpolymj.2020.110080
Abstract: Abstract Heterografted amphiphilic molecular brushes are highly grafted macromolecules with both hydrophilic and hydrophobic side chains attached to the backbone. These macromolecules display a unique combination of properties and can self-assemble in solution to form… read more here.
Keywords: synthesis self; molecular brushes; self assembly; telomerization ... See more keywords