The utility of the template effect in metal-organic frameworks
Sign Up to like & getrecommendations! Published in 2019 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2019.04.003
Abstract: Abstract This review details the emergence and continued study of the template effect in metal-organic frameworks (MOFs) with emphasis upon (i) reports of template-directed synthesis of MOFs and (ii) using MOFs as hosts to template… read more here.
Keywords: organic frameworks; effect metal; template effect; metal organic ... See more keywords
The template effect of a SiF62- guest drives the formation of a heteroleptic Fe(II) coordination helicate.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04559a
Abstract: The anion SiF62- exerts a strong template effect, driving the exclusive assembly of two different bispyridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within the large family of coordination… read more here.
Keywords: coordination; effect sif62; sif62; template effect ... See more keywords
Remote template effect in the synthesis of bipyridine-strapped porphyrins.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01697h
Abstract: A bipyridine-strapped porphyrin was prepared using a remote template effect of alkali or transition metal cations in the bipyridine subunit to enhance the yield 10-fold. The flexibility of the bipyridine-strap also allowed the synthesis of… read more here.
Keywords: remote template; bipyridine; synthesis; template effect ... See more keywords
Chiral self-organized single 2D-layers of tetramers from a functional donor-acceptor molecule by the surface template effect
Sign Up to like & getrecommendations! Published in 2023 at "Nanoscale"
DOI: 10.1039/d3nr00767g
Abstract: The ability to control the structural properties of molecular layers is a key for the design and preparation of organic electronic devices. While microscopic growth studies of planar, rigid and symmetric π-conjugated molecules have been… read more here.
Keywords: donor acceptor; template effect; surface template; surface ... See more keywords