Peroxide-Templated Assembly of a Trimetal Neodymium Complex Single-Molecule Magnet.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00234
Abstract: In this work, we present a trimetal neodymium complex with two notable qualities. First, the assembly of the complex is templated by peroxide derived from atmospheric oxygen. Second, the bulk material behaves as a superparamagnet,… read more here.
Keywords: trimetal neodymium; assembly trimetal; neodymium complex; templated assembly ... See more keywords
Cation-Templated Assembly of 613 and 623 Metalla-Links.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c13416
Abstract: Facilitated by multiple stacking interactions between components, two kinds of metalla-links containing molecular Borromean rings (623 links) and head-to-tail cyclic [3]catenanes (613 links), as isomers, were constructed in high yield by introducing tri-μ-methoxyl-dinuclear complexes [(Cp*M)2(μ-OCH3)3][OTf]… read more here.
Keywords: metalla links; 613 623; assembly 613; 623 metalla ... See more keywords
Templated co-assembly into nanorods of polyanions and artificial virus capsid proteins.
Sign Up to like & getrecommendations! Published in 2017 at "Soft matter"
DOI: 10.1039/c7sm02012k
Abstract: Recombinant triblock polypeptides C-Sn-B, where C is a 400 amino acid long hydrophilic random coil block, Sn is a multimer of the silk-like octapeptide S = (GAGAGAGQ), and B = K12 is an oligolysine, have… read more here.
Keywords: templated assembly; capsid proteins; artificial virus; microscopy ... See more keywords
Neutral isocyanide-templated assembly of pillar[5]arene [2] and [3]pseudorotaxanes.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc02255a
Abstract: Unprecedented pillar[5]arene-isocyanide pseudorotaxane complexes are reported. Extensive 1H-NMR experiments reveal remarkably strong binding affinities of alkyl diisocyanide guests (Ka > 105 M-1 in CDCl3) by pillar[5]arenes. Characterised by multinuclear 1H and 13C-NMR spectroscopy and single-crystal… read more here.
Keywords: pillar arenes; isocyanide templated; pillar arene; arene ... See more keywords
Allosteric pathway selection in templated assembly
Sign Up to like & getrecommendations! Published in 2019 at "Science Advances"
DOI: 10.1126/sciadv.aaw3353
Abstract: Allostery plays a critical role in selecting high-fidelity assembly pathways. Assembling large numbers of molecular building blocks into functional nanostructures is no trivial task. It relies on guiding building blocks through complex energy landscapes shaped… read more here.
Keywords: pathway selection; building blocks; selection templated; selection ... See more keywords
Influences of Linker and Nucleoside for the Helical Self-Assembly of Perylene Along DNA Templates
Sign Up to like & getrecommendations! Published in 2019 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2019.00659
Abstract: Six different conjugates of perylene with 2′-deoxyuridine and with 2-amino-2′-deoxyadenosine were synthesized and applied for DNA-templated assembly in aqueous buffer solutions. They differ by the linkers ethynylene, phenylene, and phenylene–ethynylene between nucleoside and chromophore. The… read more here.
Keywords: self assembly; dna; dna templates; dna templated ... See more keywords