Two SiO44--Templated Ln23Ni20 Clusters with Magnetic Cooling and Stability.
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DOI: 10.1021/acs.inorgchem.2c00802
Abstract: Assembling and studying high-nuclearity 3d-4f metal clusters represent a pregnant and challenging research hotspot. Based on anionic template and ligand-controlled hydrolytic methods, two heterometallic metal clusters, formulated as [Gd23Ni20(DTA)20(CO3)4(CH3COO)6(SiO4)4(CH3CH2OH)2(μ3-OH)33(μ2-OH)4(H2O)16]·Cl2·30H2O and [Eu23Ni20(DTA)20(CO3)4(CH3COO)6(SiO4)4(CH3CH2OH)2(μ3-OH)33(μ2-OH)4(H2O)16]·Cl2·46H2O (abbreviated as Gd23Ni20, Eu23Ni20,… read more here.
Keywords: metal clusters; two sio44; sio44 templated; templated ln23ni20 ... See more keywords