Ten-Step Asymmetric Total Synthesis of (+)-Pepluanol A.
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DOI: 10.1021/jacs.1c05257
Abstract: The first asymmetric synthesis of pepluanol A (1) is presented. The synthesis route is very concise (10 steps) and features a Curtin-Hammett-driven stereoconvergent intramolecular Diels-Alder reaction. A Nozaki-Hiyama-Kishi reaction comprises the connective step, bringing together… read more here.
Keywords: reaction; synthesis pepluanol; synthesis; ten step ... See more keywords