Pd-Catalyzed Regioselective Branched Hydrocarboxylation of Terminal Olefins with Formic Acid.
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DOI: 10.1021/acs.orglett.1c04231
Abstract: A regioselective Pd-catalyzed hydrocarboxylation of terminal olefins with HCOOH is described. A wide variety of branched carboxylic acids can readily be obtained with high regioselectivities under mild reaction conditions. The reaction is operationally simple and… read more here.
Keywords: hydrocarboxylation terminal; regioselective branched; catalyzed regioselective; terminal olefins ... See more keywords
Ti-Catalyzed Diastereoselective Cyclopropanation of Carboxylic Derivatives with Terminal Olefins.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02360
Abstract: Cyclopropanols and cyclopropylamines not only serve as important structural motifs in medicinal chemistry but also show diverse reactivities in organic synthesis. Owing to the high ring strain energy, the development of a general protocol from… read more here.
Keywords: diastereoselective cyclopropanation; derivatives terminal; carboxylic derivatives; terminal olefins ... See more keywords