New protocol of copper-catalyzed oxidative C(CO)C bond cleavage of aryl and aliphatic ketones to organic acids using O2 as the terminal oxidant
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2016.12.016
Abstract: Catalytic oxidation of CC bond is a key technology to transform petroleum-based as well as sustainable biomass feedstock into more valuable oxygenates. We herein describe a convenient and useful oxidation strategy of converting ketones into… read more here.
Keywords: bond; aliphatic ketones; copper; terminal oxidant ... See more keywords
Oxidative Dehomologation of Aldehydes with Oxygen as a Terminal Oxidant.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b03512
Abstract: A mild, efficient protocol for oxidative cleavage of C-C bonds in aldehydes has been developed that employs alkali metal hydrides as reagents and oxygen from air as a terminal oxidant. The method is applicable to… read more here.
Keywords: oxidative dehomologation; aldehydes oxygen; dehomologation aldehydes; oxygen terminal ... See more keywords
Decarboxylative Suzuki-Miyaura coupling of (hetero)aromatic carboxylic acids using iodine as the terminal oxidant.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc01817d
Abstract: A novel methodology for the decarboxylative Suzuki-Miyaura-type coupling has been established. This process uses iodine or a bromine source as both the decarboxylation mediator and the terminal oxidant, thus avoiding the need for stoichiometric amounts… read more here.
Keywords: decarboxylative suzuki; coupling hetero; hetero aromatic; suzuki ... See more keywords