Terminal Thiolate-Dominated H/D Exchanges and H2 Release: Diiron Thiol-Hydride.
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DOI: 10.1021/jacs.8b06996
Abstract: To determine the reaction pathways at a metal-ligand site in enzymes, we incorporated a terminal thiolate site into a diiron bridging hydride. Trithiolato diiron hydride, (μ-H)Fe2(pdt)(dppbz)(CO)2(SR) (1(μ-H)) [pdt2- = 1,3-(CH2)3S22-, dppbz = 1,2-C6H4(PPh2)2, RS- =… read more here.
Keywords: diiron; terminal thiolate; site; thiol hydride ... See more keywords