Reactivity Studies of [Co@Sn9]4- with Transition Metal Reagents: Bottom-Up Synthesis of Ternary Functionalized Zintl Clusters.
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DOI: 10.1021/acs.inorgchem.7b02620
Abstract: The binary cluster [Co@Sn9]4- (1) was extracted directly from ethylenediamine (en) solutions of an intermetallic precursor with nominal composition "K5Co3Sn9", and its reactions with various organometallic reagents were explored. Reaction with Ni(PPh3)2(CO)2 gives [Co@Sn9Ni(CO)]3- (2),… read more here.
Keywords: ternary functionalized; functionalized zintl; transition; transition metal ... See more keywords