Terpolymerization of β-Butyrolactone, Epoxides, and CO2: Chemoselective CO2-Switch and Its Impact on Kinetics and Material Properties
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DOI: 10.1021/acs.macromol.9b01777
Abstract: Terpolymerization reactions with a mixed-monomer feedstock of epoxides, CO2, and β-butyrolactone (BBL) at two different CO2 pressures are presented. The Lewis acidic zinc complex BDICF3–Zn–N(SiMe3)2 1 is able to catalyze both the ring-opening polymerization (ROP)… read more here.
Keywords: ring opening; terpolymerization butyrolactone; co2 chemoselective; butyrolactone epoxides ... See more keywords