Nitric oxide photo-release from a ruthenium nitrosyl complex with a 4,4′-bisfluorenyl-2,2′-bipyridine ligand
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2018.05.028
Abstract: Abstract A ruthenium nitrosyl complex of formula [RuII(terpy)(F2B)(NO)](PF6)3, where terpy stands for 2,2′:6′,2″-terpyridine and F2B for 4,4′-bis(9,9′-dibutyl-9H-fluoren-2-yl)-2,2′-bipyridine, is presented and fully characterized. The X-ray crystal structure of F2B is reported. The electronic properties of the… read more here.
Keywords: terpy; nitrosyl complex; ruthenium nitrosyl; f2b ... See more keywords
Heterocyclic nitrogen donor complexes of aluminium, gallium and indium with weakly coordinating triflate anions
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115367
Abstract: Abstract The reactions of M(OTf)3 (M = Al, Ga, In; OTf = CF3SO3–) with 2,2′:6′,2′’- terpyridyl (terpy) in CH2Cl2 gave mer-[M(OTf)3(terpy)], whilst with 2,2′-bipyridyl (bipy) and 1,10-phenanthroline (phen) the products isolated were cis-[M”(OTf)2(bipy)2]OTf (M” = Al, Ga), cis-[In(OTf)(H2O)(bipy)2][OTf]2, cis-[Al(OTf)2(phen)2][OTf]… read more here.
Keywords: otf; triflate anions; cis otf; bipy otf ... See more keywords
Creation of an unexpected plane of enhanced covalency in cerium(III) and berkelium(III) terpyridyl complexes
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-27576-y
Abstract: Controlling the properties of heavy element complexes, such as those containing berkelium, is challenging because relativistic effects, spin-orbit and ligand-field splitting, and complex metal-ligand bonding, all dictate the final electronic states of the molecules. While… read more here.
Keywords: terpy; creation unexpected; berkelium; iii ... See more keywords
How to obtain Pt(iv) complexes suitable for conjugation to nanovectors from the oxidation of [PtCl(terpyridine)].
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01706e
Abstract: Oxidation of [Pt(II)Cl(terpy)]+ (terpy = 2,2':6',2''-terpyridine) has been attempted with several oxidizing agents and under different experimental conditions in order to obtain a Pt(iv) complex suitable for the conjugation to nanovectors to be used in… read more here.
Keywords: complexes suitable; terpy; conjugation nanovectors; suitable conjugation ... See more keywords
Metallophilic interactions in silver(I) dicyanoaurate complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00615d
Abstract: This manuscript reports four new gold(I)-silver(I) complexes with 2-(2-pyridyl)-1,8-naphthyridine (pyNP) and terpyridine (terpy) as ancillary ligands, having formulae [Ag(pyNP)(Au(CN)2)]2 (1), [Ag2Au2(μ-CN)2(CN)2(pyNP)2] (2), [Ag2Au(μ-CN)2(terpy)2][Au(CN)2] (3) and [Ag4Au4(μ-CN)8(terpy)2(py)] (4). Complexes 1 and 2 are structural isomers obtained… read more here.
Keywords: metallophilic interactions; chemistry; terpy; silver dicyanoaurate ... See more keywords
Oxalate-based [CuIICrIII] coordination compounds affected by the tridentate ligand, simple anion, and reactant ratio: structural and magnetic features.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01949c
Abstract: Seven novel oxalate-based [CuIICrIII] compounds: [Cu4(terpy)4Cl5][Cr(C2O4)3]·9H2O (1; terpy = 2,2':6',2''-terpyridine), {[Cr2Cu4(H2O)2(terpy)4(C2O4)7]·10H2O}n (2), [Cr2Cu4(H2O)2(terpy)4(C2O4)7]·12H2O (3), [Cu(H2O)3(terpy)][CrCu(H2O)(terpy)(C2O4)3]2·9H2O (4), [Cu(H2O)(terpy)(NO3)][CrCu(H2O)(terpy)(C2O4)3]·6H2O (5), [CrCu2(terpy)2(C2O4)3(NO3)]·1.5H2O·CH3OH (6) and [Cr2Cu4(H2O)4(terpy)4(C2O4)6][Cr2Cu2(terpy)2(C2O4)6]·9H2O·CH3OH (7) were obtained from the reaction of an aqueous solution of the building… read more here.
Keywords: h2o terpy; ligand; terpy; c2o4 ... See more keywords
Syntheses, structures and catalytic properties of new mononuclear terpyridine-manganese(II) complexes with tetraphenylimido-diphosphinate and diphenylphosphinate ligands
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DOI: 10.1080/00958972.2019.1587163
Abstract: Abstract Treatment of manganese(II) acetate tetrahydrate [Mn(CH3COO)2·4H2O] with one equivalent of 2,2′:6′,2′′-terpyridine (terpy) and two equivalents of potassium tetraphenylimido-diphosphinate K[N(Ph2PO)2] in methanol afforded a mononuclear manganese(II) complex, [(terpy)Mn{η1-O-N(Ph2PO)2}2(H2O)] (1), with two terminal [N(Ph2PO)2]– ligands. Interaction… read more here.
Keywords: terpyridine; terpy; 4h2o one; tetraphenylimido diphosphinate ... See more keywords
Reactivity of non-organometallic ruthenium(II) polypyridyl complexes and their application as catalysts for hydride transfer reactions
Sign Up to like & getrecommendations! Published in 2023 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2023.1150164
Abstract: Recently, we investigated the substitution behavior of a series of ruthenium(II) complexes of the general formula [RuII(terpy)(N∧N)Cl]Cl, where terpy = 2,2′:6′,2″-terpyridine, N∧N = bidentate ligand, in aqueous solutions. We have shown that the most and… read more here.
Keywords: non organometallic; ruii terpy; terpy; ruthenium ... See more keywords