Synthesis, characterisation, nuclease and cytotoxic activity of phosphate-free and phosphate-containing copper $$4^{\prime }$$4′-(N-methylpyridinium)-$$2{,}2^{\prime }{:}6^{\prime }{,}2^{\prime \prime }$$2,2′:6′,2″ terpyridine complexes
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-018-1422-7
Abstract: Mononuclear Cu(II) pyridinium terpyridine based compounds, viz., [Cu(q- pytpy)(I)$$(\hbox {CH}_{3}\hbox {COO})](\hbox {I})\cdot (2\hbox {H}_{2}\hbox {O})$$(CH3COO)](I)·(2H2O) (1) and [Cu(dipp)(dippH)(q-pytpy)]$${\cdot }(2\hbox {H}_{2}\hbox {O}$$·(2H2O)(DMF) (2) were isolated by reacting $$\hbox {Cu}(\hbox {OAc})_{2}{\cdot }\hbox {H}_{2}\hbox {O}$$Cu(OAc)2·H2O with $$4^{\prime }$$4′-(N-methylpyridinium)-2,$$2^{\prime… read more here.
Keywords: terpyridine; cytotoxic; hbox hbox; prime prime ... See more keywords
Self-healing organogels and hydrogels constructed by self-assembled bis-terpyridine complex with selective metal ions
Sign Up to like & getrecommendations! Published in 2020 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"
DOI: 10.1016/j.colsurfa.2020.124439
Abstract: Abstract Terpyridine-based gels represent a new type of metallogels due to the facile synthesis and tunable properties. However, few of them could form super gel with remarkably self-healing properties. Herein, a novel kind of bis-terpyridine… read more here.
Keywords: terpyridine; bis terpyridine; terpyridine complex; self healing ... See more keywords
Theoretical insights into the sensing mechanism of a series of terpyridine-based chemosensors for TNP
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DOI: 10.1016/j.cplett.2019.03.041
Abstract: Abstract It is of high importance to develop high-efficient chemosensors for explosive nitroaromatics and explore their sensing mechanisms. In this work, the sensing mechanisms of a series of arylene-vinylene terpyridine conjugated fluorescent probes (P1-P4) for… read more here.
Keywords: theoretical insights; sensing mechanism; terpyridine; insights sensing ... See more keywords
Synthesis, crystal structure, and density functional theory study of a zinc(II) complex containing terpyridine and pyridine-2,6-dicarboxylic acid ligands: Analysis of the interactions with amoxicillin
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DOI: 10.1016/j.crci.2018.11.007
Abstract: Abstract An octahedral zinc(II) complex of 2,2′:6′,2″-terpyridine (Tpy) and pyridine-2,6-dicarboxylate (Pydc), [Zn(II)(Tpy)(Pydc)·4H2O] was synthesized and its structure was determined by a single-crystal X-ray diffraction. The ligand pyridine-2,6-dicarboxylate coordinated to the zinc(II) ion via two pairs… read more here.
Keywords: tpy pydc; pydc 4h2o; theory; terpyridine ... See more keywords
Synthesis, characterization, DNA binding, topoisomerase I inhibition and antiproliferation activities of three new functionalized terpyridine platinum(II) complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2018.12.003
Abstract: Three new platinum(II) complexes with pendent morpholine were synthesized, namely complex 1 ([Pt(L)Cl]CF3SO3), complex 2 ([Pt(L)(NH3)](CF3SO3)2) and complex 3 ([Pt(L)(PPh3)](CF3SO3)2), where L = 4'-[4-(4-morpholinobutyloxy)phenyl]-2,2':6',2″-terpyridine and PPh3 = triphenylphosphine. The detailed molecular structures of complex 3, L and its precursor… read more here.
Keywords: terpyridine; dna; three new; activities three ... See more keywords
{Ru(CO)x}-core terpyridine complexes: Lysozyme binding affinity, DNA and photoinduced carbon monoxide releasing properties
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Photochemistry and Photobiology A: Chemistry"
DOI: 10.1016/j.jphotochem.2018.06.026
Abstract: Abstract Reaction of 4′-(2-pyridyl)-2,2′:6′,2″-terpyridine (LPY) and 4′-(4-phenylmorpholine)-2,2′:6′,2″-terpyridine (Lmorph) with {[RuCl2(CO)3]}2 in methanol affords [RuCl2(LPY-κ2N1N2)(CO)2] (1) and a mixture of [RuCl2(Lmoph-κ2N1N2)(CO)2]/[RuCl2(Lmorph-κ3N1N2N3)(CO)] (2), respectively. Their photoactivatable CO releasing properties are investigated upon the exposure to light source… read more here.
Keywords: terpyridine; dna; releasing properties; lysozyme binding ... See more keywords
Studies on preparation, crystal structure, thermal properties and fluorescence properties of rare earth complexes composed of 2-chloro-4-fluorobenzoic acid and 2,2':6′,2″-terpyridine
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DOI: 10.1016/j.jssc.2021.122633
Abstract: Abstract Four new 2D complexes namely [Ln(2-Cl-4-FBA)3(terpy)H2O] (Ln=Er(1),Ho(2)); [Eu(2-Cl-4-FBA)3(terpy)H2O]·1.5H2O(3); [Tb(2-Cl-4-FBA)3(terpy)H2O]·2H2O (4); (2-Cl-4-FBA=2-chloro-4-fluorobenzoate,terpy=2,2':6′,2 ″-terpyridine) were synthesized at normal temperature. The structures of complexes were determined by single-crystal X-ray diffraction. The results show that the two complexes… read more here.
Keywords: terpyridine; fluorescence; studies preparation; terpy h2o ... See more keywords
Influence of structural changes on photophysical properties of terpyridine derivates: Experimental studies and theoretical calculations
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.10.011
Abstract: Abstract Four terpyridine ligands containing different aryl substituents 4'-(4-quinolinyl)-3,2':6′,3″-terpyridine (3-qtpy), 4'-(4-quinolinyl)-2,2':6′,2″-terpyridine (2-qtpy), 4'-(3-methyl-2-thienyl)-4,2':6′,4″-terpyridine (4-stpy) and 4'-(3-methyl-2-thienyl)-2,2':6′,2″-terpyridine (2-stpy) were synthesized in a one-pot procedure and characterized by elemental analysis, FT-IR and 1H- and 13C NMR spectroscopy.… read more here.
Keywords: structural changes; influence structural; terpyridine; changes photophysical ... See more keywords
Photophysical investigaions and the bioimaings of α-, β-, γ-pyridine-based terpyridine derivatives
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DOI: 10.1016/j.molstruc.2017.12.101
Abstract: Abstract Three unprecedented triphenylamine-based D-A type terpyridine derivatives (TriphenL1-TriphenL3) with different positions of nitrogen atom in the terpyridine moiety were carefully designed and fully characterized, which was further confirmed via single-crystal X-ray diffraction determination. The… read more here.
Keywords: terpyridine; bioimaings pyridine; pyridine based; terpyridine derivatives ... See more keywords
Panchromatic sensitization of new terpyridine ligated thiocyanate-free Ru-complex
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DOI: 10.1016/j.solener.2019.06.012
Abstract: Abstract Two new thiocyanato-free Ru sensitizers GS1 and GS2 having substitutions at the central pyridyl group of the terpyridine ligand successfully synthesized. GS1 and GS2 were used as photosensitizers for DSSCs devices. These sensitizers were… read more here.
Keywords: panchromatic sensitization; gs1 gs2; new terpyridine; terpyridine ... See more keywords
Water Molecule-Induced Reversible Magnetic Switching in a Bis-Terpyridine Cobalt(II) Complex Exhibiting Coexistence of Spin Crossover and Orbital Transition Behaviors.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00818
Abstract: The development of molecule-based switchable materials remains an important challenge in the field of molecular science. Achievement of a structural phase transition induced by adsorption/desorption of guest molecules in spin crossover (SCO) Co(II) compounds is… read more here.
Keywords: molecule; terpyridine; transition; phase transition ... See more keywords