Synthesis and Properties of Covalently Linked Terpyridine‐BODIPY and Terpyridine‐3‐Pyrrolyl BODIPY Conjugates
Sign Up to like & getrecommendations! Published in 2024 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202400693
Abstract: A series of covalently linked terpyridine‐BODIPY and terpyridine‐3‐pyrrolyl BODIPY conjugates were synthesized by strategically tuning the position of the terpyridine moiety at the α and/or meso positions of the BODIPY (3‐4) and 3‐pyrrolyl BODIPY cores… read more here.
Keywords: pyrrolyl bodipy; linked terpyridine; terpyridine; bodipy ... See more keywords
The Anti‐Cancer Stem Cell Properties of Copper(II)‐Terpyridine Complexes with Attached Salicylaldehyde Moieties
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DOI: 10.1002/cbic.202400703
Abstract: We report the synthesis, characterisation, and anti‐breast cancer stem cell (CSC) properties of two copper(II)‐terpyridine complexes with bidentate salicylaldehyde moieties (2‐hydroxybenzaldehyde for 1 and 2‐hydroxy‐1‐naphthaldehyde for 2). The copper(II)‐terpyridine complexes 1 and 2 are stable… read more here.
Keywords: stem cell; terpyridine complexes; salicylaldehyde moieties; cancer stem ... See more keywords
Does the central nitrogen atom make a difference? A comparison of non‐coordinating pyridine and benzene spacers in multitopic ligands
Sign Up to like & getrecommendations! Published in 2024 at "Helvetica Chimica Acta"
DOI: 10.1002/hlca.202400023
Abstract: In metal coordination compounds of the divergent ligands 4,2':6',4"‐terpyridine and 3,2':6',3"‐terpyridine and their 4'‐functionalized derivatives, the central pyridine ring of the 4,2':6',4"‐terpyridine and 3,2':6',3"‐terpyridine domains is non‐coordinated. We present an overview of data from the… read more here.
Keywords: benzene; terpyridine terpyridine; central nitrogen; terpyridine ... See more keywords
Effect of density functional approximations on the calculated Jahn–Teller distortion in bis(terpyridine)manganese(III) and related compounds
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Molecular Modeling"
DOI: 10.1007/s00894-023-05812-0
Abstract: Context Bis(terpyridine)manganese(III) exhibits Jahn–Teller distortion due to the inequivalent occupation of the degenerate e _ g orbitals of this high-spin d^4 pseudo octahedral complex. Due to the spatially constrained nature of the terpyridine ligand, the… read more here.
Keywords: jahn teller; bis terpyridine; terpyridine; terpyridine manganese ... See more keywords
Synthesis, characterisation, nuclease and cytotoxic activity of phosphate-free and phosphate-containing copper $$4^{\prime }$$4′-(N-methylpyridinium)-$$2{,}2^{\prime }{:}6^{\prime }{,}2^{\prime \prime }$$2,2′:6′,2″ terpyridine complexes
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-018-1422-7
Abstract: Mononuclear Cu(II) pyridinium terpyridine based compounds, viz., [Cu(q- pytpy)(I)$$(\hbox {CH}_{3}\hbox {COO})](\hbox {I})\cdot (2\hbox {H}_{2}\hbox {O})$$(CH3COO)](I)·(2H2O) (1) and [Cu(dipp)(dippH)(q-pytpy)]$${\cdot }(2\hbox {H}_{2}\hbox {O}$$·(2H2O)(DMF) (2) were isolated by reacting $$\hbox {Cu}(\hbox {OAc})_{2}{\cdot }\hbox {H}_{2}\hbox {O}$$Cu(OAc)2·H2O with $$4^{\prime }$$4′-(N-methylpyridinium)-2,$$2^{\prime… read more here.
Keywords: terpyridine; cytotoxic; hbox hbox; prime prime ... See more keywords
Self-healing organogels and hydrogels constructed by self-assembled bis-terpyridine complex with selective metal ions
Sign Up to like & getrecommendations! Published in 2020 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"
DOI: 10.1016/j.colsurfa.2020.124439
Abstract: Abstract Terpyridine-based gels represent a new type of metallogels due to the facile synthesis and tunable properties. However, few of them could form super gel with remarkably self-healing properties. Herein, a novel kind of bis-terpyridine… read more here.
Keywords: terpyridine; bis terpyridine; terpyridine complex; self healing ... See more keywords
Theoretical insights into the sensing mechanism of a series of terpyridine-based chemosensors for TNP
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2019.03.041
Abstract: Abstract It is of high importance to develop high-efficient chemosensors for explosive nitroaromatics and explore their sensing mechanisms. In this work, the sensing mechanisms of a series of arylene-vinylene terpyridine conjugated fluorescent probes (P1-P4) for… read more here.
Keywords: theoretical insights; sensing mechanism; terpyridine; insights sensing ... See more keywords
Synthesis, crystal structure, and density functional theory study of a zinc(II) complex containing terpyridine and pyridine-2,6-dicarboxylic acid ligands: Analysis of the interactions with amoxicillin
Sign Up to like & getrecommendations! Published in 2019 at "Comptes Rendus Chimie"
DOI: 10.1016/j.crci.2018.11.007
Abstract: Abstract An octahedral zinc(II) complex of 2,2′:6′,2″-terpyridine (Tpy) and pyridine-2,6-dicarboxylate (Pydc), [Zn(II)(Tpy)(Pydc)·4H2O] was synthesized and its structure was determined by a single-crystal X-ray diffraction. The ligand pyridine-2,6-dicarboxylate coordinated to the zinc(II) ion via two pairs… read more here.
Keywords: tpy pydc; pydc 4h2o; theory; terpyridine ... See more keywords
Synthesis, characterization, DNA binding, topoisomerase I inhibition and antiproliferation activities of three new functionalized terpyridine platinum(II) complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2018.12.003
Abstract: Three new platinum(II) complexes with pendent morpholine were synthesized, namely complex 1 ([Pt(L)Cl]CF3SO3), complex 2 ([Pt(L)(NH3)](CF3SO3)2) and complex 3 ([Pt(L)(PPh3)](CF3SO3)2), where L = 4'-[4-(4-morpholinobutyloxy)phenyl]-2,2':6',2″-terpyridine and PPh3 = triphenylphosphine. The detailed molecular structures of complex 3, L and its precursor… read more here.
Keywords: terpyridine; dna; three new; activities three ... See more keywords
{Ru(CO)x}-core terpyridine complexes: Lysozyme binding affinity, DNA and photoinduced carbon monoxide releasing properties
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Photochemistry and Photobiology A: Chemistry"
DOI: 10.1016/j.jphotochem.2018.06.026
Abstract: Abstract Reaction of 4′-(2-pyridyl)-2,2′:6′,2″-terpyridine (LPY) and 4′-(4-phenylmorpholine)-2,2′:6′,2″-terpyridine (Lmorph) with {[RuCl2(CO)3]}2 in methanol affords [RuCl2(LPY-κ2N1N2)(CO)2] (1) and a mixture of [RuCl2(Lmoph-κ2N1N2)(CO)2]/[RuCl2(Lmorph-κ3N1N2N3)(CO)] (2), respectively. Their photoactivatable CO releasing properties are investigated upon the exposure to light source… read more here.
Keywords: terpyridine; dna; releasing properties; lysozyme binding ... See more keywords
Studies on preparation, crystal structure, thermal properties and fluorescence properties of rare earth complexes composed of 2-chloro-4-fluorobenzoic acid and 2,2':6′,2″-terpyridine
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2021.122633
Abstract: Abstract Four new 2D complexes namely [Ln(2-Cl-4-FBA)3(terpy)H2O] (Ln=Er(1),Ho(2)); [Eu(2-Cl-4-FBA)3(terpy)H2O]·1.5H2O(3); [Tb(2-Cl-4-FBA)3(terpy)H2O]·2H2O (4); (2-Cl-4-FBA=2-chloro-4-fluorobenzoate,terpy=2,2':6′,2 ″-terpyridine) were synthesized at normal temperature. The structures of complexes were determined by single-crystal X-ray diffraction. The results show that the two complexes… read more here.
Keywords: terpyridine; fluorescence; studies preparation; terpy h2o ... See more keywords