Formation of Terrestric Acid in Penicillium crustosum Requires Redox-Assisted Decarboxylation and Stereoisomerization.
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DOI: 10.1021/acs.orglett.9b04002
Abstract: Crustosic acid (1) differs from terrestric acid (2) by a 5β-carboxylmethyl at the tetronate ring instead of a 5α-methyl group in Penicillium crustosum. The formation of 1 via carboxylcrustic and viridicatic acid was confirmed by… read more here.
Keywords: terrestric acid; assisted decarboxylation; decarboxylation; penicillium crustosum ... See more keywords