Micro-solvation and counter ion effects on ionic reactions: Activation of potassium fluoride with 18-crown-6 and tert-butanol in aprotic solvents
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2020.114211
Abstract: Abstract Ionic reactions have an important solvent effect and the first solvation shell makes the most important contribution for determining the reactivity. In the case of nucleophilic fluorination with potassium fluoride, the solubilization of the… read more here.
Keywords: potassium fluoride; butanol; tert butanol; ionic reactions ... See more keywords
Systematic approach for screening organic and ionic liquid solvents in homogeneous extractive distillation exemplified by the tert-butanol dehydration
Sign Up to like & getrecommendations! Published in 2019 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2018.10.030
Abstract: Abstract A systematic strategy for the screening of organic solvents and ionic liquids as entrainers along with the design of the corresponding homogeneous extractive distillation processes has been developed. The proposed approach is illustrated by… read more here.
Keywords: extractive distillation; screening organic; tert butanol; homogeneous extractive ... See more keywords
Isobaric Vapor–Liquid Equilibrium for Binary and Ternary Systems of tert-Butanol + tert-Butyl Acetate + Chlorobenzene at 101.33 kPa
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical & Engineering Data"
DOI: 10.1021/acs.jced.7b01021
Abstract: Isobaric vapor–liquid equilibria of tert-butanol + chlorobenzene and tert-butyl acetate + chlorobenzene binary systems and the tert-butanol + tert-butyl acetate + chlorobenzene ternary system at 101.33 kPa were measured using a circulation VLE still. The… read more here.
Keywords: tert butyl; tert butanol; acetate chlorobenzene; tert ... See more keywords
Hierarchical ZSM-5 Zeolite with Enhanced Catalytic Activity for Alkylation of Phenol with Tert-Butanol
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DOI: 10.3390/catal9020202
Abstract: Using polyethylene glycol as a mesoporous soft template, a series of hierarchically porous ZSM-5 zeolites were prepared. X-ray diffraction, infrared spectroscopy, N2 adsorption–desorption, and transmission electron microscopy results demonstrated that the resultant materials contained a… read more here.
Keywords: hierarchical zsm; phenol tert; tert butanol; alkylation phenol ... See more keywords