Synthesis and derivatisation of ceric tris(tert-butoxy)siloxides.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06499c
Abstract: Metathesis reactions involving cerium(iv) complexes are generally hampered by a high tendency for reduction to the favoured trivalent state and a preference for ligand redistribution. Heteroleptic ceric Ce[OSi(OtBu)3]3Cl(thf) is easily obtained from the oxidation of… read more here.
Keywords: derivatisation ceric; osi otbu; synthesis derivatisation; tert butoxy ... See more keywords
Molecular engineering low-surface energy membranes by grafting perfluoro-tert-butoxy chains containing fluorous silica aerogels
Sign Up to like & getrecommendations! Published in 2020 at "Green Chemistry"
DOI: 10.1039/d0gc00593b
Abstract: The recent attention on perfluorinated superhydrophobic membranes has been accompanied by growing concerns over the potential degradation of longer than C6-perfluoroalkyl chain containing compounds in the environment to form bioaccumulating perfluoroalkyl acids. While maintaining the… read more here.
Keywords: tert butoxy; surface; perfluoro tert; low surface ... See more keywords