Organometallic-Mediated Alternating Radical Copolymerization of tert-Butyl-2-Trifluoromethacrylate with Vinyl Acetate and Synthesis of Block Copolymers Thereof.
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201700203
Abstract: Organometallic-mediated radical polymerization (OMRP) has given access to well-defined poly(vinyl acetate-alt-tert-butyl-2-trifluoromethacrylate)-b-poly(vinyl acetate) and poly(VAc-alt-MAF-TBE) copolymers composed of two electronically distinct monomers: vinyl acetate (VAc, donor, D) and tert-butyl-2-trifluoromethacrylate (MAF-TBE, acceptor, A), with low dispersity (≤1.24)… read more here.
Keywords: tert butyl; vinyl acetate; butyl trifluoromethacrylate;
Enhanced Fluorescence Properties of Stilbene-Containing Alternating Copolymers.
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DOI: 10.1002/marc.201700530
Abstract: In recent years, nonconjugated, fluorophore-free organic polymers have emerged as potentially useful light-emitting materials. The fluorescence properties of a novel class of nonconjugated, tert-butyl carboxylate functionalized stilbene-containing alternating copolymers are investigated in this work. These… read more here.
Keywords: fluorescence; alternating copolymers; fluorescence properties; stilbene containing ... See more keywords
Design, synthesis, in vitro determination and molecular docking studies of 4-(1-(tert-butyl)-3-phenyl-1H-pyrazol-4-yl) pyridine derivatives with terminal sulfonamide derivatives in LPS-induced RAW264.7 macrophage cells
Sign Up to like & getrecommendations! Published in 2021 at "Medicinal Chemistry Research"
DOI: 10.1007/s00044-021-02784-9
Abstract: In the present work, a new series of 4-(1-(tert-butyl)-3-phenyl-1H-pyrazol-4-yl) pyridine possessing terminal ethyl or propyl sulfonamides was designed and synthesized. The cytotoxic effect of the final compounds was measured by applying MTT assay in LPS-Induced… read more here.
Keywords: raw264 macrophage; lps induced; butyl phenyl; tert butyl ... See more keywords
A new and convenient approach for the synthesis of P-stereogenic intermediates bearing a tert-butyl(methyl)phosphino group
Sign Up to like & getrecommendations! Published in 2017 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-017-2923-6
Abstract: Chiral organophosphorus compounds possessing a P-stereogenic center have been widely used as agricultural chemicals, pharmaceuticals, organocatalysts, and ligands for transition-metal catalysis. P-Stereogenic intermediates bearing a tert-butyl(methyl)phosphino group are important for the preparation of several commonly… read more here.
Keywords: phosphino group; tert butyl; stereogenic intermediates; methyl phosphino ... See more keywords
Theoretical study on mechanism of reaction between tert-butyl isocyanide and dimethyl acetylenedicarboxylate in presence of ethanethiol or thiophenol
Sign Up to like & getrecommendations! Published in 2018 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-018-3252-0
Abstract: The mechanism of the multicomponent reaction between tert-butyl isocyanide and dimethyl acetylenedicarboxylate in presence of ethanethiol and thiophenol (as SH-acid) was investigated theoretically. According to quantum-mechanical computations, four different pathways (I, II, III, and IV)… read more here.
Keywords: mechanism; butyl isocyanide; tert butyl; reaction ... See more keywords
Synthesis, structure, and magnetic properties of magnesium bis-3,6-di-tert-butyl-о-benzosemiquinonate complexes with N-donor ligands
Sign Up to like & getrecommendations! Published in 2017 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-017-1933-2
Abstract: A series of six-coordinate magnesium bis-3,6-di-tert-butyl-о-benzosemiquinonate complexes with different N-donor ligands (2,2´-dipyridyl, 1,10-phenanthroline, 2,9-dimethyl-1,10-phenanthroline, pyridine, N-phenyl-1-(4-pyridinyl)methanimine) were synthesized. The molecular and crystal structures of these complexes were determined by X-ray diffraction. In the complexes with… read more here.
Keywords: bis tert; donor ligands; tert butyl; benzosemiquinonate complexes ... See more keywords
Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system
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DOI: 10.1007/s11172-018-2234-0
Abstract: Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system allows one to synthesize with high rates and yield fully soluble polybutadiene with controlled molecular characteristics. It was shown that the obtained cationic polybuta… read more here.
Keywords: cationic polymerization; using titanium; butadiene using; polymerization butadiene ... See more keywords
Copper(ii) compounds with cetyltrimethylammonium bromide as an efficient catalytic system for tert-butyl hydroperoxide decomposition
Sign Up to like & getrecommendations! Published in 2020 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-020-2721-y
Abstract: Chelate compounds of copper(ii) demonstrated high catalytic activity in tert-butyl hydroperoxide decomposition in the presence of cetyltrimethylammonium bromide (CTAB). The feature of this catalytic system is that it ensures high reaction rate without visible sign… read more here.
Keywords: cetyltrimethylammonium bromide; system; hydroperoxide decomposition; tert butyl ... See more keywords
Effect of the Phase Composition of Molybdenum Boride on its Catalytic Properties in the Epoxidation of 1-Octene by tert-Butyl Hydroperoxide
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DOI: 10.1007/s11237-019-09588-4
Abstract: It was shown that the epoxidation of 1-octene by tert-butyl hydroperoxide in the presence of Mo2B is accompanied by the formation of an amorphous oxygen-containing phase on its surface. It was established that this is… read more here.
Keywords: phase; epoxidation octene; octene tert; tert butyl ... See more keywords
Magnetic Properties of bis-o-Benzosemiquinonato Cobalt(II), Iron(II), and Manganese(II) Complexes with 2,2'-Biquinoline and 1,4-Di-tert-Butyl-1,4-Diazabutadiene
Sign Up to like & getrecommendations! Published in 2020 at "Theoretical and Experimental Chemistry"
DOI: 10.1007/s11237-020-09663-1
Abstract: New heteroligand cobalt(II), iron(II), and manganese(II) complexes of the M(3,6-SQ)2L type bearing 3,6-di-tert-butyl-o-benzosemiquinonato ligands (3,6-SQ) and 2,2'-biquinoline or 1,4-di-tert-butyl-1,4-diazabutadiene-1,3 as neutral ligands (L) have been synthesized and characterized. It was shown on the basis of… read more here.
Keywords: cobalt iron; tert butyl; manganese complexes;
Fate of bis-(4-tert-butyl phenyl)-iodonium under photolithography relevant irradiation and the environmental risk properties of the formed photoproducts
Sign Up to like & getrecommendations! Published in 2022 at "Environmental Science and Pollution Research"
DOI: 10.1007/s11356-022-19376-8
Abstract: Aryl-iodonium salts are utilized as photoacid generators (PAGs) in semiconductor photolithography and other photo-initiated manufacturing processes. Despite their utilization and suspected toxicity, the fate of these compounds within the perimeter of semiconductor fabrication plants is… read more here.
Keywords: tert butyl; bis tert; phenyl iodonium; butyl phenyl ... See more keywords