Copper-Assisted Direct Nitration of Cyclic Ketones with Ceric Ammonium Nitrate for the Synthesis of Tertiary α-Nitro-α-substituted Scaffolds.
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DOI: 10.1021/acs.orglett.7b00040
Abstract: An efficient and direct Cu-assisted nitrating approach to create synthetically valuable and challenging tertiary α-nitro-α-substituted moieties has been developed using ceric ammonium nitrate as a nitrating reagent, oxidant, and Lewis acid. Notably, the commonly used… read more here.
Keywords: ceric ammonium; ammonium nitrate; nitro substituted; tertiary nitro ... See more keywords