Asymmetric C-Alkylation of Nitroalkanes via Enzymatic Photoredox Catalysis.
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DOI: 10.1021/jacs.2c12197
Abstract: Tertiary nitroalkanes and the corresponding α-tertiary amines represent important motifs in bioactive molecules and natural products. The C-alkylation of secondary nitroalkanes with electrophiles is a straightforward strategy for constructing tertiary nitroalkanes; however, controlling the stereoselectivity… read more here.
Keywords: asymmetric alkylation; alkylation nitroalkanes; alkylation; nitroalkanes via ... See more keywords