A Unified Approach to Lactonization/Lactamization by Leveraging Tether-Tunable Distonic Radical Anions.
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DOI: 10.1021/acs.orglett.5c00185
Abstract: We report using visible-light-induced in situ generation of tether-tunable distonic radical anions for the general catalytic lactonization/lactamization of aromatic carboxylic acids and benzamides. Its success relies on the specific cyclic diacyl peroxide and catalytic amount… read more here.
Keywords: radical anions; tether tunable; distonic radical; lactonization lactamization ... See more keywords