Bisannulation of Benzamides and Cyclohexadienone-Tethered Allenes Triggered by Cp*Rh(III)-Catalyzed C-H Activation and Relay Ene Reaction.
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DOI: 10.1021/acs.orglett.8b00083
Abstract: The diastereoselective bisannulation of N-(pivaloyloxy)benzamides and cyclohexadienone-tethered allenes was accomplished through Cp*Rh(III)-catalyzed C-H activation and relay ene reaction, providing a 3-isoquinolonyl cis-hydrobenzofuran framework with high yields and diastereoselectivities. This reaction tolerates a wide range of… read more here.
Keywords: iii catalyzed; tethered allenes; catalyzed activation; benzamides cyclohexadienone ... See more keywords