Linear Inverse Sandwich Complexes of Tetraanionic Benzene Stabilized by Covalent δ-Bonding with Late Lanthanides
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DOI: 10.1021/jacs.4c12278
Abstract: A series of dilanthanide benzene inverse sandwich complexes of the type (CpiPr5Ln)2(μ–η6:η6-C6H6) (1-Ln) (Ln = Y, Gd, Tb, Dy, Tm) are reported. These compounds are synthesized by reduction of the respective trivalent dimers CpiPr52Ln2I4 (Ln… read more here.
Keywords: inverse sandwich; tetraanionic benzene; covalent bonding; sandwich complexes ... See more keywords