DFT studies on the structure and stability of tetraaza macrocyclic nickel(II) complexes containing dicarbinolamine ligand moiety
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DOI: 10.1007/s12039-019-1688-4
Abstract: Density functional theory calculations at M052X/6-311++G** level were performed to understand the structure and stability of Ni(II) tetraaza macrocyclic dicarbinolamine complex 1. The preferential stability of 1 over the hitherto unknown Ni(II) complex having fully… read more here.
Keywords: dicarbinolamine; structure; structure stability; stability ... See more keywords
Electrocatalytic oxidation of water using self-assembled copper(ii) tetraaza macrocyclic complexes on a 4-(pyridine-4′-amido)benzene grafted gold electrode
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DOI: 10.1039/d1nj00630d
Abstract: Gold surface anchored copper(ii)tetraaza macrocyclic complex showed an excellent electrocatalytic activity towards water oxidation with an overpotential of 284 mV at a current density of 1.31 mA cm−2 and a Tafel slope of 48 mV… read more here.
Keywords: tetraaza macrocyclic; copper tetraaza; gold;
Synthesis and Characterization of Zinc(II) Tetraaza Macrocyclic Complexes with Aquo and Nitrate Ligands
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DOI: 10.5012/jkcs.2018.62.1.14
Abstract: The complexes [Zn(L)(H2O)2]⋅2NO2 (1) and [Zn(L)(NO3)2] (2) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo [14,4,0,0]docosane) have been synthesized and structurally characterized. The compound 1 crystallizes in the monoclinic system P21/c with a = 8.74650(10), b = 18.6880(3), c =… read more here.
Keywords: nitrate ligands; zinc; characterization zinc; zinc tetraaza ... See more keywords