Tetracoordinate borates as catalysts for reductive formylation of amines with carbon dioxide
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DOI: 10.1039/d0gc01741h
Abstract: We report sodium trihydroxyaryl borates as the first robust tetracoordinate organoboron catalysts for reductive functionalization of CO2. These catalysts, easily synthesized from condensing boronic acids with metal hydroxides, activate main group element–hydrogen (E–H) bonds efficiently.… read more here.
Keywords: formylation; reductive formylation; tetracoordinate borates; catalysts reductive ... See more keywords