Organocatalytic iminium-assisted asymmetric B(sp²)-to-B(sp³) transformation
Sign Up to like & getrecommendations! Published in 2025 at "Nature Communications"
DOI: 10.1038/s41467-025-65393-9
Abstract: Tetracoordinate boron compounds are widely used as dyes in medicinal research and material sciences. Current methods for accessing such compounds with a stereogenic boron center rely on chiral substrate-induced diastereoselective reactions or metal-catalyzed desymmetrization of… read more here.
Keywords: boron; iminium; center; transformation ... See more keywords
Recent advances in the construction of tetracoordinate boron compounds.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06982b
Abstract: Tetracoordinate boron compounds are a highly important class of molecules, which are the key intermediates in many organoboron-related chemical transformations and have unique luminescence properties. However, the synthesis of tetracoordinate boron compounds has never been… read more here.
Keywords: boron compounds; tetracoordinate boron; boron; construction ... See more keywords
Access to tetracoordinate boron-doped polycyclic aromatic hydrocarbons with delayed fluorescence and aggregation-induced emission under mild conditions
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc01722a
Abstract: Boron-doped polycyclic aromatic hydrocarbons (PAHs) have attracted ongoing attention in the field of optoelectronic materials due to their unique optical and redox properties. To investigate the effect of tetracoordinate boron in PAHs bearing N-heterocycles (indole… read more here.
Keywords: tetracoordinate boron; emission; boron; boron doped ... See more keywords
Benzo-Extended N^N^N-Chelated Tetracoordinate Boron Hetero[8]Helicene Featuring an Inner N‒B‒N Helical Rim for Circularly Polarized TADF
Sign Up to like & getrecommendations! Published in 2025 at "Journal of Materials Chemistry C"
DOI: 10.1039/d5tc02210j
Abstract: The synthesis of tetracoordinate boron helicenes bearing B–N units aligned along the inner rim of the helical backbone remains exceedingly rare due to steric hindrance. We present the design and... read more here.
Keywords: benzo extended; chelated tetracoordinate; tetracoordinate; tetracoordinate boron ... See more keywords