CSiGaAl2−/0 and CGeGaAl2−/0 having planar tetracoordinate carbon atoms in their global minimum energy structures
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26845
Abstract: Density functional theory (DFT) is used to explore the structure, stability, and bonding in CSiGaAl2−/0 and CGeGaAl2−/0 systems having planar tetracoordinate carbon (ptC). The neutral systems have 17 valence electrons and the mono‐anionic systems have… read more here.
Keywords: valence; tetracoordinate carbon; csigaal2 cgegaal2; planar tetracoordinate ... See more keywords
CAl11-: a molecular rotor with a quasi-planar tetracoordinate carbon.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00855j
Abstract: In this work, we analyzed the bonding and fluxional character of the global minimum of CAl11-. Its structure is formed by two stacked layers, one of them resembles the well-known planar tetracoordinate carbon CAl4 on… read more here.
Keywords: cal11 molecular; molecular rotor; tetracoordinate carbon; planar tetracoordinate ... See more keywords