Generation [via Tetradehydro-Diels-Alder Reactions] and Reactivity of 6-Fluorocyclohexa-1,2,4-triene Intermediates.
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DOI: 10.1021/acs.orglett.5c03636
Abstract: We report the engagement of the 2,6-difluorophenyl substituent in tetradehydro-Diels-Alder (TDDA) reactions. The use of fluorine was guided by DFT computations. Acceleration of TDDA cycloisomerization by an anhydride linker in the substrates was also key.… read more here.
Keywords: generation via; via tetradehydro; tetradehydro diels; diels alder ... See more keywords