Iron(ii) tetrafluoroborate complexes of new tetradentate C-scorpionates as catalysts for the oxidative cleavage of trans-stilbene with H2O2.
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DOI: 10.1039/c9dt02829c
Abstract: Attachment of a 2-methylpyridyl group onto the unique 1-nitrogen atom on nitrogen-confused C-scorpionates with either pyrazol-1-yl or 3,5 dimethylpyrazol-1-yl donors gives two new cis-directing tetradentate-N4 ligands (L and L*). The complexes [(L or L*)Fe(CH3CN)2](BF4)2 (1… read more here.
Keywords: tetradentate; cleavage; complexes new; trans stilbene ... See more keywords