Trapping of a Terminal Intermediate in the Boron-Mediated Dinitrogen Reduction: Mono-, Tri-, and Tetrafunctionalized Hydrazines in Two Steps from N2.
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DOI: 10.1021/jacs.4c01818
Abstract: The addition of chlorotrimethylsilane to a boron-mediated, transition-metal-free N2 activation reaction leads to the isolation of multiple potassium boryl(silyl)hydrazido species, likely trapping products of a terminal dinitrogen complex of boron. One of these silylated N2… read more here.
Keywords: boron mediated; tetrafunctionalized hydrazines; two steps; boron ... See more keywords