Hypoelectronic titanaboranes: icosahedral and tetracapped tetrahedral clusters comprising bridging hydrides.
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DOI: 10.1039/d4cc06535b
Abstract: Unusual hypoelectronic closo-clusters, such as icosahedral [(Cp*Ti)3(B9H7)(μ3-H)(μ3-Cl)2] (1) and tetracapped tetrahedral [{(Cp*Ti)3B}(μ3-BH3)2(μ3-Te)2] (2), have been synthesized and structurally characterized. Clusters 1 and 2 represent the first examples of closo-titanaboranes having bridging hydrides, where the Ti⋯Ti… read more here.
Keywords: tetracapped tetrahedral; icosahedral tetracapped; titanaboranes icosahedral; tetrahedral clusters ... See more keywords
Reminiscence of a Magnetization Plateau in a Magnetization Processes of Toy-Model Triangular and Tetrahedral Clusters
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Experimental and Theoretical Physics"
DOI: 10.1134/s106377611903004x
Abstract: We discuss magnetization curves of a toy-model trigonal and tetrahedral clusters. Nonlinearity of magnetization with local minimum of differential susceptibility resembling known magnetization plateaus of triangular-lattice and pyrochlore lattice antiferromagnets is observed at intermediate temperature… read more here.
Keywords: toy model; tetrahedral clusters; magnetization; reminiscence magnetization ... See more keywords