Spontaneous Resolution upon Crystallization and Preferential Induction of Chirality in a Discrete Tetrahedral Zinc(II) Complex Comprised of Achiral Precursors.
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DOI: 10.1021/acs.inorgchem.9b01934
Abstract: A pair of enantiomeric tetrahedral complexes (Λ-[Zn(L)2] and Δ-[Zn(L)2]) comprised of the achiral ligand methyl-3-hydroxy-3-phenyl-2-propenedithioate (L) have been synthesized by spontaneous resolution. Two chiral inducers, viz., d-(-)- and l-(+)-tartaric and mandelic acids, have been employed… read more here.
Keywords: comprised achiral; tetrahedral zinc; zinc complex; spontaneous resolution ... See more keywords